Plants can use both the ammonium and nitrate forms of nitrogen.
But the nitrate form is more susceptible to leaching. It poses more
risk to groundwater.
Nitrification is a process in which bacteria convert ammonium forms
of nitrogen into nitrate forms. Nitrification inhibitors are chemicals
designed to slow this process, reducing the risk that nitrogen will
be lost through leaching and denitrification. (With denitrification,
soil organisms convert nitrate-nitrogen into a form that is unavailable
to the plants. )
Inhibitors are most useful in the following situations:
When the soil is moderately or well-drained and is in an area
of heavy rainfall or frequent flooding.
When you apply nitrogen in the fall, ammonium forms of N have
more time to convert into nitrate forms. Inhibitors reduce this
risk.
If
you apply nitrogen with inhibitors in the fall, make applications
after the soil temperature has dropped below 60 degrees F and the
soil is likely to be frozen for most of the winter.
Inhibitors
work best when nitrogen is applied at or below optimum levels. They
are not necessary if you put down nitrogen right before the crop needs
it or as a sidedressing application.
Inhibitors
do not work as well in extremely coarse soils, unless nitrogen applications
are managed carefully. In coarse soils, ammonium nitrogen has a tendency
to move away from the inhibitors.